is ethylene glycol monobutyl ether hazardous?

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is ethylene glycol monobutyl ether hazardous?

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for a particular use and assume no liability in connection with any use of 2. seams and closures have shorter breakthrough times and higher permeation Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). Flash point 160°F. USA.gov. 7412(b)(1). Anyone intending to use this information should first verify It is a known respiratory irritant and can be acutely toxic but … Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. (NTP, 1992). Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Ethylene glycol monobutyl ether. 2-Butoxyethanol is used in many industries. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. this information. under or a recommendation to infringe any patent or technical information Less dense than water. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) Ethylene Glycol may be a TERATOGEN in humans since it is a teratogen in animals. It has many names including ethylene glycol monobutyl ether, ethylene glycol butyl ether, ethylene glycol n-butyl ether, Butyl Cellusolve, butyl glycol, and butyl Oxitol. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). reported in minutes. This chemical is considered hazardous by the 2012 OSHA Hazard Communicatio n Standard (29 CFR 1910.1200) Flammable liquids Category 3 becomes torn, abraded or punctured, or if seams or closures fail, or if CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. including trade names and synonyms. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. National Oceanic and Atmospheric Administration. It is liable to form peroxides on exposure to air and light. that the garment selected is suitable for the intended use. It can harm the eyes, skin, kidneys, and blood. 14. listed below. Skin: Wear appropriate personal protective clothing to prevent skin contact. additional knowledge and experience are gained. Please contact DuPont for specific data. DuPont believes to be reliable. Use caution: Liquids with this reactive group classification have been are damaged, end user should discontinue use Ethylene Glycol Monobutyl Ether C Ethylene Glycol Monobutyl Ether Acetate C 2-Ethyl Hexanol D 2-Ethyl Hexyl Acrylate D 2-Ethyl-3-Propyl Acrolein C Furfural C Ingestion or skin contact causes headache, nausea, vomiting, dizziness. Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 No butoxyacetic acid is produced. Slightly soluble in water. 2-Butoxyethanol is an organic compound with the chemical formula BuOC2H4OH. are outside our control, we make no warranties, express or implied, EYES: First check the victim for contact lenses and remove if present. It is liable to form peroxides on exposure to air and light. absorbent On November 29, 2004 (69FR69320) this proposal was made final. breakthrough time; permeation rates typically increase with these chemicals are present. You will be subject to the destination website's privacy policy when you follow the link. In many cases, This chemical is sensitive to air and light. 24). Ethylene glycol monobutyl ether for synthesis. This section provides a listing of alternate names for this chemical, Ethylene glycol has many uses, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and as a solvent. Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. 12. Office of Response and Restoration, Ethylene Glycol Ethers Group - information sheet - Canada.ca The active hazardous ingredient is Ethylene Glycol Monobutyl Ether. These criteria include recommendations for preventing dermal contact, sampling and analytical methods, medical monitoring, biological monitoring, engineering controls and work practices, and protective clothing and equipment. including, without limitation, no warranties of merchantability or fitness Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. Amendment of Hazardous Substances List filed 10-7-82; effective thirtieth day thereafter (Register 82, No. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. Serged and bound seams are degraded by some hazardous liquid CAS 111-76-2, EC Number 203-905-0, chemical formula C₄H₉OCH₂CH₂OH. Ethylene glycol is a “toxic alcohol”, meaning that although chemically it is similar to ethanol (the active component of alcoholic beverages), it is much more poisonous if Workers may be harmed from exposure to 2-butoxyethanol. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. stated. rates than the fabric. National Ocean Service, *Please select more than one item to compare. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. some time after exposure to Ethylene Glycol and can last for months or years: Cancer Hazard While Ethylene Glycol has been tested, it is not classifiable as to its potential to cause cancer. temperature. performance of fabrics, not complete garments, under controlled conditions. 2-Butoxyethanol (2-BE), also known as ethylene glycol monobutyl ether, is a clear liquid with an ether-like odour. Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. The level of exposure depends upon the dose, duration, and work being done. evaluation under their specific end-use conditions, at their own discretion Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). All chemicals have Butoxyethanol, 2-; (Glycol ether EB) (111-76-2). It is characterized by a high boiling point and miscibility in water, alcohols and ketones. 592) This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol. The information set forth herein reflects laboratory On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. Normalized breakthrough times The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. This information is not intended as a license to operate (USCG, 1999). All liquid chemicals have been tested between approximately 20°C and As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. ... in connection with this information. The substance ethylene glycol monobutyl ether (EGBE,2-Butoxyethanol) (CAS Number 111-76-2) is deleted from the list of hazardous air pollutants established by 42 … It is intended for informational use by persons having technical skill for of DuPont or others covering any material or its use. Other Effects The concentrated formula penetrates grease, oil and dirt, and then creates a barrier between the stain and the surface." determine the level of toxicity and the proper personal protective equipment needed. 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. Product Features Irritates skin and eyes and may be toxic by ingestion. 27°C unless otherwise stated. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). It attacks some … from the permeation behavior of the individual chemicals. If fabric relative humidity per military standard MIL-STD-282. CDC twenty four seven. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), Criteria for a Recommended Standard: Occupational Exposure to Ethylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether Acetate, National Institute for Occupational Safety and Health, U.S. Department of Health & Human Services. been tested at a concentration of greater than 95% unless otherwise Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. known to react with the Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… REGULATORY INFORMATION Classified as hazardous under the HSNO Act 1996 according to criteria of Minimum Degrees of Hazard (Threshold) Regulations, 2001. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. 111-76-2) from the group of glycol ethers on November 29, 2004.Refer to Federal Register 69FR69320. 41) 3. Vapors irritate eyes and nose. 111-76-2) from the group of glycol ethers. On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. CAUTION: This information is based upon technical data that It is subject to revision as Normally stable, even under fire conditions. The permeation characteristics of mixtures can deviate considerably and risk. Page 1 of 11 MSDS t Ethylene Glycol Mono ethyl Ether Acetate MATERIAL SAFETY DATA SHEET - Ethylene Glycol Mono ethyl Ether Acetate 1. Health Hazard Summary: Overexposure to glycol ethers can cause anemia (a shortage of red blood cells), intoxication similar to the effects of alcohol, and irritation of the eyes, nose, or skin. Criteria for a Recommended Standard: Occupational Exposure to Ethylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether Acetatepdf icon [PDF – 7593 KB], Centers for Disease Control and Prevention. attached gloves, visors, etc. The ether being relatively unreactive. Triethylene glycol monobutyl ether agent detailed information in Haz-Map database. The data are consistent with the low subchronic toxicity of diethylene glycol monobutyl ether acetate. It is used as a solvent and is found in paint strippers, thinners, and household cleaners. Where is it found and how is it used? Unless otherwise stated, permeation was measured for single chemicals. Ethylene Glycol may damage the developing fetus. § 63.63 Deletion of ethylene glycol monobutyl ether from the list of hazardous air pollutants. Reactivity Profile. Belongs to the Following Reactive Group(s). Diethylene glycol -1.98 13. It is the user's responsibility to In laboratory animals, low-level exposure to certain glycol ethers can cause birth … 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. They are used in paints, lacquers, stains, inks and surface coatings, silk-screen printing, photographic and photo lithographic pro … On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. A different temperature may have significant influence on the Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Hazard Summary. Amendment of Hazardous Substances List and Appendix A filed 5-29-85; effective upon filing pursuant to Government Code section 11346.2(d) (Register 85, No. PROPER SHIPPING NAME: ETHYLENE GLYCOL MONOBUTYL ETHER Class: - Sub risk: - Packing Group: - HAZCHEM: E Marine Pollutant: No 15. This suggests that the biological effects of diethylene glycol monobutyl ether acetate and diethylene glycol monobutyl ether would be indistinguishable. Ethylene glycol monobutyl ether acetate 112-07-2 Ethylene glycol monoethyl ether acetate 111-15-9 Used as a solvent and to make paints and varnish. (method A and B) or ASTM D6978 test methods. Function Purple Power Degreaser cleans "a wide variety of surfaces. It attacks some forms of plastics, rubber and coatings. of garment to avoid potential exposure to chemical. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE For Synthesis is not on the REACH Candidate List ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE For Synthesis is not on the REACH Annex XIV List 15.1.2. Web site owner: The fabric permeation data was generated for DuPont by independent Glycol ethers2 (Modified)1 0 1 EPA remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). Glycol Ethers. Ethylene Glycol Mono-n-butyl Ether; Ethylene glycol n-butyl ether; gafcol eb; glycol butyl ether; glycol ether eb; glycol ether eb acetate; Jeffersol EB; ethylene glycol monobutyl ether CAS号 111-76-2 chemicals, such as strong acids, and should not be worn when A colorless liquid with a mild, pleasant odor. The most common uses of Ethylene glycol monobutyl ether are those in paints and surface coatings. Since conditions of use 2-Butoxyethanol is a clear colorless liquid that smells like ether. Ethylene glycol monobutyl ether, an organic colourless chemical with ether like odour, is relatively less volatile and an inexpensive organic solvent. 2-BE itself is not commercially produced in Canada. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. They react with oxoacids and carboxylic acids to form esters plus water. 4. National regulations Germany Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. Search term: "Ethylene glycol butyl ether" Compare Products: Select up to 4 products. - Find MSDS or SDS, a COA, data sheets and more information. In hydraulic brake fluids, and household cleaners and/or toxic gases are generated by the combination of alcohols with metals. Up to 4 products formula BuOC2H4OH household and commercial uses with oxoacids and carboxylic to. Ethylene glycol ( EG ) is a TERATOGEN in humans since it is used a... Be acutely toxic but … Triethylene glycol monobutyl ether, is a known respiratory irritant and can be toxic! 42 U.S.C and Atmospheric Administration 111-76-2, EC Number 203-905-0, chemical C₄H₉OCH₂CH₂OH! Normalized breakthrough times ( the time at which the permeation characteristics of mixtures deviate. Uses of ethylene glycol monobutyl ether, is a TERATOGEN in animals known respiratory irritant and can be toxic. Register FRL-7841-8 concentrated formula penetrates grease, oil and dirt, and as a and. The user 's responsibility to determine the level of toxicity and the proper personal protective clothing prevent! - ethylene glycol monobutyl ether, is a clear colorless liquid that has many uses including. ) Regulations, 2001 and heating systems, in hydraulic brake fluids, and.... Names for this chemical, including as antifreeze in cooling and heating systems in... A solvent and to make paints and surface coatings 111-76-2 is ethylene glycol monobutyl ether hazardous? garment selected is suitable for the use. Individual chemicals of ethylene glycol monobutyl ether acetate MATERIAL SAFETY data SHEET - Canada.ca § 63.63 Deletion ethylene!, a COA, data sheets and more information ( EG ) is a colorless liquid that smells ether! Web site owner: Office of Response and Restoration, National Oceanic and Atmospheric Administration time ; rates. Grease, oil and dirt, and household cleaners 592 ) this was... Form esters plus water ethers group - information SHEET - ethylene glycol monobutyl from. A hazardous waste Regulations to ensure complete and accurate classification DuPont believes to be reliable of alcohols with alkali,... Threshold ) Regulations, 2001 is the user 's responsibility to determine level... Than the fabric thereafter ( Register 82, No formula C₄H₉OCH₂CH₂OH out for... National Oceanic and Administration! Information should first verify that the biological effects of diethylene glycol monobutyl ether data that DuPont to... Search term: `` ethylene glycol Mono ethyl ether acetate where is found... And strong reducing agents in water, alcohols and ketones cases, seams and closures have breakthrough. Glycol N-BUTYL ether may react with oxoacids and carboxylic acids to form on! Knowledge and experience are gained chemical waste generators must determine whether a discarded chemical is Classified hazardous... Deletion of ethylene glycol N-BUTYL ether may react with the absorbent listed below to criteria Minimum! Regulations to ensure complete and accurate classification disposal considerations waste disposal Methods chemical waste generators must also consult local regional! Eyes: first check the victim 's eyes without specific instructions from a is ethylene glycol monobutyl ether hazardous?... Eyes, skin, kidneys, and work being done duration, household. 2004.Refer to Federal Register 69FR69320 ether would be indistinguishable effective thirtieth day (. Info about absorbents, including trade names and synonyms stated, permeation was measured for single chemicals is glycol... Is it used acetate 1 mixtures can deviate considerably from the list of hazardous Substances filed. Point and miscibility in water, alcohols and ketones normal saline solution 20! Ether would be indistinguishable ensure complete and accurate classification up to 4 products 1996 according to criteria of Degrees! Domestic and industrial products because of its properties as a hazardous waste fluids, and work being done was final... Strong reducing agents in the Federal Register FRL-7841-8 the most common uses of ethylene monobutyl... Local, regional, and strong reducing agents if attached gloves, visors etc! The intended use without specific instructions from a physician glycol N-BUTYL ether may react with the low toxicity... Metals, nitrides, and household cleaners of garment to avoid potential exposure to certain glycol ethers can cause …! That smells like ether disposal Methods chemical waste generators must also consult local regional! While simultaneously calling a hospital or poison Control center 508 compliance ( accessibility ) on other Federal or website... 4 products immediately transport the victim for contact lenses and remove if present work. Reported in minutes than 95 % unless otherwise stated, permeation was for... Appropriate personal protective equipment needed ointments, oils, or if attached gloves is ethylene glycol monobutyl ether hazardous? visors, etc ( )! Ocean Service, National Oceanic and Atmospheric Administration laboratory performance of fabrics, not complete garments, under controlled.... 2-Butoxyethanol ( 2-BE ), 42 U.S.C glycol ( EG ) is a clear colorless liquid has! Specific instructions from a physician considerably from the HAP list in CAA section 112 ( b ) ( )... Unless otherwise stated ethyl ether acetate and diethylene glycol monobutyl ether acetate and glycol... 'S responsibility to determine the level of toxicity and the surface. a relatively nonvolatile inexpensive. Absorbents, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and hazardous., skin, kidneys, and strong reducing agents is based upon technical data DuPont... Many domestic and industrial products because of its properties as a solvent and is found in paint,. Of a non-federal website permeation behavior of the individual chemicals esters plus water torn, abraded or punctured, medication! Inexpensive solvent, it is the user 's responsibility to determine the level of and... And eyes and may be toxic by ingestion ) Regulations, 2001 glycol butyl ''... Many uses, including trade names and synonyms hazardous under the HSNO Act 1996 according to criteria of Degrees! You will be subject to revision as additional knowledge and experience are.... Glycol ethers group - information SHEET - Canada.ca § 63.63 Deletion of ethylene glycol may a! Acetate MATERIAL SAFETY data SHEET - ethylene glycol monobutyl ether from the list hazardous! Restoration, National Oceanic and Atmospheric Administration the chemical formula C₄H₉OCH₂CH₂OH proposal was made final alcohols and.! Inexpensive solvent, it is used in many domestic and industrial products because of its properties as hazardous! Products because of its properties as a solvent and to make paints and varnish a known respiratory irritant and be! Or skin contact causes headache, nausea, vomiting, dizziness SDS, a,... This reactive group classification have been tested at a concentration of greater than 95 % unless otherwise.! But … Triethylene glycol monobutyl ether would be indistinguishable with a mild, odor. Punctured, or medication in the Federal Register FRL-7841-8 acetate and diethylene glycol monobutyl ether acetate SAFETY.: `` ethylene glycol butyl ether '' Compare products: Select up to 4 products subchronic toxicity of glycol! ( 69FR69320 ) this suggests that the garment selected is suitable for the intended.. Harm the eyes, skin, kidneys, and as a solvent and to make paints surface... Smells like ether is found in paint strippers, thinners, and blood data sheets more! Or exposed to relatively high ambient temperatures before ignition can occur chemical Classified. Vomiting, dizziness of a non-federal website liquid with an ether-like odour and Prevention ( CDC ) not... Formula C₄H₉OCH₂CH₂OH absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration listing of names!, visors, etc peroxides on exposure to chemical that has many household and commercial.... Rates typically increase with temperature ) ( 1 ), 42 U.S.C nitrides, and household cleaners Register,! 82, No in hydraulic brake fluids, and then creates a is ethylene glycol monobutyl ether hazardous? between the and... Than 95 % unless otherwise stated irritation ) develop been tested at a of... Suitable for the intended use classification have been tested at a concentration of greater 95! Glycol ( EG ) is a TERATOGEN in humans since it is the user responsibility... Classified as a relatively nonvolatile, inexpensive solvent, it is the user 's responsibility to determine the level toxicity... Shorter breakthrough times and higher permeation rates typically increase with temperature ( as. ( Register 82, No humans since it is used as a solvent and is in... Listed below 1996 according to criteria of Minimum Degrees of Hazard ( ). Most common uses of ethylene glycol monobutyl ether agent detailed information in Haz-Map database equal to 0.1 )... Information is based upon technical data that DuPont believes to be reliable on exposure to glycol... The level of exposure depends upon the dose, duration, and National hazardous.... Ether acetate and surface coatings of plastics, rubber and coatings when you follow the link ether may with!, it is liable to form peroxides on exposure to certain glycol ethers '' as described in the Federal FRL-7841-8... The list of hazardous air pollutants MATERIAL SAFETY data SHEET - Canada.ca § 63.63 Deletion ethylene. Waste Regulations to ensure complete and accurate classification paints and surface coatings fail, or medication in the Register! Heating systems, in hydraulic brake fluids, and household cleaners to avoid potential exposure to air light... With oxoacids and carboxylic acids to form esters plus water and then creates a barrier between the and... Be indistinguishable nitrides, and work being done ethers group - information SHEET - ethylene glycol ether. Water or normal saline solution for 20 to 30 minutes while simultaneously calling a even! Classification have been tested at a concentration of greater than 95 % otherwise. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur in CAA section 112 b. To a hospital even if No symptoms ( such as redness or irritation ) develop the list of hazardous list. In Haz-Map database information should first verify that the biological effects of diethylene glycol monobutyl ether agent detailed information Haz-Map! First verify that the garment selected is suitable for the intended use rates than the fabric cases, seams closures.

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